Optimasi formula plasticizer gliserol dan filler carboxymethyl cellulose terhadap kekuatan mekanik pada biodegradable film packaging berbasis pati singkong

Siti Munfarida, Amalia Nur Kumalaningrum, Nita Ariestiana Putri, Jefri Pandu Hidayat, Rizka Ayu Yuniar, Lasma Barbara Naibaho

Abstract

The use of conventional plastics, which are difficult to degrade, has caused serious environmental problems, necessitating alternatives in the form of biodegradable plastics (bioplastics). Biofilms are anticipated to address social issues in line with the 12th SDG goal, namely the management and reduction of packaging waste generated daily. By utilizing abundant local cassava starch, the produced biofilms are anticipated to possess good mechanical properties and low water absorption, making them a potential eco-friendly alternative for food packaging while supporting the use of local resources. This study aims to develop cassava starch-based biofilms as environmentally friendly packaging by optimizing the formulation of carboxymethyl cellulose (CMC) and glycerol. The research employs cassava starch as the primary matrix, CMC as a filler to enhance mechanical properties, and glycerol as a plasticizer to improve the flexibility of the biofilm. The research methods include cassava starch extraction, mixing of materials with stirring and heating, and drying the gel into a biofilm. The biofilm's characteristics were analyzed through tensile strength and elongation tests. The results showed that the formula with a cassava starch concentration of 15 grams, 1% CMC, and 6% glycerol yielded the highest tensile strength value of 1.56 MPa, meeting the Japanese Industrial Standard (JIS) for edible films (≥ 0.392 MPa). The best elongation value reached 199.6%, demonstrating excellent flexibility according to JIS and Indonesian National Standards (SNI). This study indicates that the appropriate combination and concentration of materials can produce biofilms with the potential to replace conventional plastics, support environmental sustainability, and optimally utilize local resources

Keywords

Biodegradable film; Carboxymethyl cellulose; Gliserol; Kekuatan mekanik; Pati singkong

References

Agung N.C.S, dan Arruum L.O., 2017. Sintesis Dan Karakterisasi Bioplastik Dari Kitosan-Pati Ganyong (Canna Edulis). Jurnal Kimia Dan Pendidikan Kimia. Vol 2(1): 13-21. DOI : 10.20961/jkpk.v2i1.8526

Ashoka G., Anuradhi L., Asanga M., Chamila G., Sudhagar M., Othmane M., and Terrence M., 2022. Applications of Starch Biopolymers for a Sustainable Modern Agriculture. Sustainability. 14(10), 6085; https://doi.org/10.3390/su14106085

Deivy A.P., Yoni M. P, Sahadi D.I., 2024. Variasi Penambahan Gliserol Pada Pembuatan Bioplastik Limbah Cair Tahu. Jurnal Teknologi Pertanian Andalas Vol. 28, No.1, ISSN 1410-1920, EISSN 2579-4019

Dewi, S.R., Widyasanti, A. and Putri, S.H., 2023. Pengaruh Konsentrasi Pati Singkong terhadap Karakteristik Edible Film Berbahan Pati Singkong dengan Penambahan Ekstrak Daun Belimbing Wuluh. Jurnal Keteknikan Pertanian Tropis dan Biosistem, 11(2), pp. 158–167.

F Maruddin, R Malaka, S Baba, H Amqam, M Taufik and S Sabil, 2020. Brightness, elongation and thickness of edible film with caseinate sodium using a type of plasticizer. IOP Conf. Ser.: Earth Environ. Sci. 492 012043 DOI 10.1088/1755-1315/492/1/012043

Fahrullah F., Djoko K., Bulkaini B., Haryanto H., Baiq R.D.W., Wahid Y., Azhary N., Vebera M., 2023. The Effects of Plasticizer Types on Properties of Whey-Gelatin Films. Jurnal Biologi Tropis. 23 (3): 414 – 421. DOI: http://dx.doi.org/10.29303/jbt.v23i3.5283

Intandiana, S., Dawam, A.H., Denny, Y.R. & Septiyanto, R.F. 2019. 'Pengaruh Karakteristik Bioplastik Pati Singkong dan Selulosa Mikrokristalin Terhadap Sifat Mekanik dan Hidrofobisitas', EduChemia (Jurnal Kim. dan Pendidikan), 4(2), p. 185. doi: 10.30870/educhemia.v4i2.5953.

Irawan, Y., Wulandari, Y. W. & Karyantina, M., 2017. Kerupuk sayur dengan variasi konsentrasi bubur sawi hijau (Brassica rapa) dan rasio tepung terigu-tapioka. Jurnal Teknologi dan Industri Pangan 2(1), 1-7

Japanese Industrial Standard (JIS). 2019. General Rules of Plastic Film for Food Packaging. Tokyo: JSA.

Katiany M.T., Adriana d.C., Bruno R.L., Ana A.R., Juliano E.D.O., José M.M., 2020. Effect of carboxymethyl cellulose concentration on mechanical and water vapor barrier properties of corn starch films. Carbohydrate Polymers. Vol 246: 11652. Doi: https://doi.org/10.1016/j.carbpol.2020.116521

Muhammad A., Nanik W., Sri M., 2018. Pembuatan dan Karakterisasi Bioplastik dari Pati Biji Alpukat-Kitosan dengan Plasticizer Sorbitol. Indo. J. Chem. Sci. 7 (2). doi: http://journal.unnes.ac.id/sju/index.php/ijcs

Muhammed L. S., Salit M. S., Mohammad J., Mohamad R. I., and Japar S., 2015. Effect of Plasticizer Type and Concentration on Tensile, Thermal and Barrier Properties of Biodegradable Films Based on Sugar Palm (Arenga pinnata) Starch. Polymers 7(6), 1106-1124; https://doi.org/10.3390/polym7061106

Muin, R., Anggraini, D., & Malau, F., 2017. Karakteristik Fisik dan Antimikroba Edible Film Dari Tepung Tapioka Dengan Penambahan Gliserol Dan Kunyit Putih‖, Jurnal Teknik Kimia, 23(3), 191–198.

Pramiati P., 2016. Upaya Mengurangi Timbulan Sampah Plastik Di Lingkungan. Indonesian Journal Of Urban And Environmental Technology, 8(2), 141-147. https://doi.org/10.25105/urbanenvirotech.v8i2.1421

Putri, D. A., Setiawan, A., & Anggraini, P. D. 2018. Physical Properties of Edible Sorgum Starch Film Added with Carboxymethyl Cellulose. Journal Of Physical Science, 29, 185-194.

Rahul T., Penta P., Christopher J. S., Michael B., S.P. Singh., Quan V. V., 2019. Starch-based films: Major factors affecting their properties. International Journal of Biological Macromolecules. Vol. 132: 1079-1089. https://doi.org/10.1016/j.ijbiomac.2019.03.190

Rinku V., Vinoda K.S., Papireddy M., Gowda A.N.S., 2016. Toxic Pollutants from Plastic Waste- A Review. Procedia Environmental Sciences. Volume 35: 701-708. https://doi.org/10.1016/j.proenv.2016.07.069

Rozanna D., Rahmi, Nasrun, 2021. Perbaikan Sifat Mekanik Dan Laju Transmisi Uap Air Edible Film Bioplastik Menggunakan Minyak Sawit Dan Plasticizer Gliserol Berbasis Pati Sagu. Jurnal Teknologi Kimia Unimal 10 (1): 61-77

Sanyang, M.L., Sapuan, S.M., Jawaid, M., Ishak, M.R. & Sahari, J. 2016. Effect of Sugar Palm-derived Cellulose Reinforcement on the Mechanical and Water Barrier Properties of Sugar Palm Starch Biocomposite Films. BioResources, 11(2), pp. 4134-4145. doi: 10.15376/biores.11.2.4134-4145.

Sri A., 2019. Pemanjangan % Elongation Plastik Biodegradable. Fakultas Teknik Universitas Wahis Hasyim: Semarang.

Warkoyo, Ardiana D. A. T., Rista A., 2021. Karakteristik Edible Film Berbasis Gel Buah Okra (Abelmoschus Esculentus L) Dengan Penambahan Cmc (Carboxy Methyl Cellulose) Dan Gliserol. Agrointek Volume 15: 704-714

Yuli D., Ridho H., Lia L., Herti U., 2017. Pengaruh Konsentrasi Plasticizer Gliserol Terhadap Karakteristik Komposit Bioplastik Berbasis Pati Sorgum. Seminar Nasional Riset dan Industri 2016. 94-100

Yusuf E.P., Zulferiyenni, Fibra N., Susilawati, 2024. Karakteristik Biodegradable Film Berbasis Selulosa Kelobot Jagung (Zea Mays) Dengan Penambahan Gliserol Dan Carboxy Methyl Cellulose (CMC). Jurnal Agroindustri Berkelanjutan Vol. 3 (1)

DOI

https://doi.org/10.21107/agrointek.v20i1.28410

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