HIGH VALUED  LIMONENE IN ESSENTIAL OIL EXTRACT FROM LIME PEEL WASTE FOR PARFUM INDUSTRY

Rosdanelli Hasibuan; Rita Sundari; Elisabeth Gultom; Rini Anggraini; Juliza Hidayati

doi:10.21107/agrointek.v15i4.10098

HIGH VALUED LIMONENE IN ESSENTIAL OIL EXTRACT FROM LIME PEEL WASTE FOR PARFUM INDUSTRY

Rosdanelli Hasibuan, Rita Sundari, Elisabeth Gultom, Rini Anggraini, Juliza Hidayati

Abstract

Limonene in essential oils is highly valuable attracts great interest of consumers due to its specific fragrance. It is not surprising that many big perfume industries are looking for high purified limonene found in essential oils of certain fruits and flowers. This study investigates the extraction process of essential oil from lime peel waste. This study has used two extraction methods, i.e. maceration method and Soxhlet technique. Two types of organic solvent applied, i.e. hexane and ethanol. This work studies the effect of extraction time, type of organic solvent, and extraction method on yield of extraction. Characterization studies as FTIR (Fourier Transform Infra Red) Spectroscopy related to type of chemical bonding of limonene in essential oil and GC-MS (Gas Chromatography – Mass Spectrometry) related to limonene fragmentation have also investigated.

Keywords

essential oil; extraction; lime peel waste; limonene; maceration; Soxhlet.

Full Text:

PDF

References

Ahmad, A., Alkarkhi, A., Hena, S., Siddique, B., and Dur, K. (2010). Optimization of Soxhlet extraction of herbal Leonuri using factorial design of experiment. International Journal of Chemistry, 2(1), 198-205. https://doi.org/10.5539/ijc.v2n1p198

Alhassan, M., Lawal, A, Nasiru, Y., Suleiman, M., Safiya, A. M., and Bello, N. (2018). Extraction and formulation of perfume from locally available lemon grass leaves. ChemSearch Journal, 9(2), 40-44. www.ajol.info › index.php › csj › article

Baser, K.H.C., and Buchbauer, G. (2010). Handbook of Essential Oils: Science, Technology, and Applications. Publisher: 1st ed., CRC Press –Taylor & Francis Group, New York, London. https://doi.org/10.1201/9781420063165

Bawono, R.E., Saryanto, H., and Sebayang, D. (2021). Analisis pengaruh perlakuan kavitasi ultrasonic terhadap struktur mikro pada daun tanaman nilam (Pogostemon cablin Benth) (Analysis of treatment effect of ultrasonic cavitation on micro structure of patchouli leaves). Agrointek, 14(2). (in Indonesian).

Buckle, J. (2015). Basic plant taxonomy, basic essential oil chemistry, extraction, biosynthesis, and analysis in Clinical Aromatherapy. https://doi.org/10.1016/B978-0-7020-5440-2.00003-6

Chisvert, A., and Salvador, A. (2007). Analysis of Cosmetic Products. Publisher: Elsevier, 1st ed., USA. https://doi.org/10.1016/B978-0-444-52260-3.X5020-7

Chouchi, D., and Barth, D. (1994). Rapid identification of some coumarin derivatives in deterpenated citrus peel oil by gas chromatography. Journal of Chromatography A, 672(1-2), 177-183.

https://doi.org/10.1016/0021- 9673(94)80606-3

Clarke, S. (2008). Essential Chemistry for Aromatherapy. Publisher: Churchill Livingstone Elsevier, 2nd ed., USA. https://doi.org/10.1016/B978-0-443-10403-9.X0001-5

Hasibuan, R., and Gultom, E. (2020). The effect of method, type of solvent and extraction time towards the yield of oil on essential oil extraction from lime peel (Citrus aurantifolia). Proceedings of the 3rd Talenta Conference on Engineering Science and Technology, Medan, September 28-29, 2020. ocs.usu.ac.id › schedConfs › archive

Lestari, A., and Arreneuz, S. (2014). Uji bioaktivitas minyak atsiri kulit buah jeruk Pontianak (Citrus nobilis Lour) terhadap rayap tanah (Coptotermes curvignathus sp) (Examination of bioactivity of essential oils of Pontianak orange peel (Citrus nobilis Lour) on subterranean termites (Coptotermes curvignathus sp), Jurnal Kimia Khatulistiwa, 3(2), 38-43. (in Indonesian). www. jurnal.untan.ac.id › article › view

Njoku, V. I., and Evbuomwan, B.O. (2014). Utilization of essential oil and pectin extracted from Nigerian orange peels. Greener Journal of Chemical Science and Technology, 1(1), 006-014. https://doi.org/10.15580/GJCST.2014.1.041414186

Pavia, D. L., Lampman, G. M., Kris, G. S., and Vyvyan, J. R. (2009). Introduction to Spectroscopy. Publisher: Books/Cole Cengage Learning, 4th ed., USA.

Reverchon, E., and Marrone, C. (1997). Supercritical extraction of clove bud essential oil: isolation and mathematical modeling. Chemical Engineering Science, 52(20), 3421-3428. https://doi.org/10.1016/S0009-2509(97)00172-3

Sari, D., Oktaviana, H., and Ningsih, O. C. (2016). Aromatic compounds production by fungal solid state fermentation in Pandanus tectorius fruits. Biosciences Biotechnology Research Asia, 13(1), 75-78. https://doi.org/10.13005/bbra/2005

Sugiantoro, Afghani, J., Andi, H., and Alimuddin. (2016). Biotransformasi limonen dari minyak atsiri kulit jeruk Pontianak menggunakan jamur Rhizopus oligosporus dalam media air kelapa (Biotransformation of limonene from essential oil Pontianak orange peels applying Rhizopus oligosporus fungi in coconut water media). Jurnal Kimia Khatulistiwa, 5(3), 40-44 (in Indonesian). www. jurnal.untan.ac.id › article › view

Tesfaye, B., and Tefera, T. (2017). Extraction of essential oil from neem seed by using Soxhlet extraction methods. Journal of Advanced Engineering, Management and Science, 3(6), 646-650. https://dx.doi.org/10.24001/ijaems.3.6.5

Thao, N., Kashiwagi, T., and Sawamura, M. (2014). Characterization by GC-MS of Vietnamese citrus species and hybrids based on the isotope ratio of monoterpene hydrocarbons. Bioscience, Biotechnology, and Biochemistry, 71(9), 2155-2161. https://doi.org/10.1271/bbb.70069

Triesty, I., and Mahfud, M. (2017). Ekstraksi minyak atsiri dari gaharu (Aquilaria malaccensis) dengan menggunakan metoda microwave hydrodistillation dan Soxhlet extraction (Extraction of essential oils from aloes (Aquilaria malaccensis) applying microwave hydrodistillation and Soxhlet extraction methods). Jurnal Teknik Institut Teknologi Surabaya, 6(2), 392-395 (in Indonesian). ejurnal.its.ac.id › article

Wibaldus, Jayuska, A., and Ardiningsih, P. (2016). Bioaktivtas minyak atsiri kulit buah jeruk nipis (Citrus aurantifolia) terhadap rayap tanah (Coptotermes sp) (Bioactivity of essential oils lime peels (Citrus aurantifolia) on subterranean termites (Coptotermes sp). Jurnal Kimia Khatulistiwa, 5(1) , 44-51 (in Indonesian). www. jurnal.untan.ac.id › article › view