Pemutihan Kertas Koran Bekas dengan Menggunakan Asam Peroksida dalam Media Asam Asetat

Sri Hidayati; Ahmad Sapta Zuidar; Rachmania Widyastuti

doi:10.21107/agrointek.v12i1.3243

Pemutihan Kertas Koran Bekas dengan Menggunakan Asam Peroksida dalam Media Asam Asetat

Sri Hidayati, Ahmad Sapta Zuidar, Rachmania Widyastuti

Abstract

Used newsprint is one of the most potential materials to be recovered into pulp raw material. The problem is the color of newsprint that requires bleaching process. One of the oxidizing agents used for bleaching is the peroxide acid in the acetic acid medium. The purpose of this research is to know the effect of peroxide acid concentration in acetic acid media and the duration of heating to the chemical properties of pulp produced. The best results were obtained at 12% per oxide acid concentration in acetic acid medium and 5 hour heating time, yielding 58.653% cellulose, hemicellulose 9,033%, lignin 22,683%, and color score 4,503% (rather white).

Keywords

cellulose;hemicelulose;lignine

Full Text:

PDF (Bahasa Indonesia)

References

Achmadi, S .S. 1990. Kimia Kayu. Departemen Pendidikan dan Kebudayaan. Direktoran Jendral Pendidikan Tinggi Pusat Antar universitas Ilmu Hayat. Institut Pertanian Bogor. 105 hlm.

Aremu, M. O., Aperolola, S. O and Dabonyan, O. O., (2015), Suitability of Nigerian Corn Husk and Plantain Stalk For Pulp and Paper Production, European Scientific Journal , Vol.11 (30), pp. 146-152.

Arifin. 2008. Industri Pulp Dan Kertas: Ancaman Baru Terhadap Hutan Alam Indonesia. wordpress.com/2008/01/19/industri-pulp-dan-kertas-ancaman-baru-terhadap-hutan-alam-indonesia/

Batubara, R. 2006. Teknologi Bleaching Ramah Lingkungan. Fakultas Pertanian. Karya Tulis. Universitas Sumatera Utara. Hlm 1-6

Barr, C. 2001. The Financial Collapse of asi Pulp & Paper: Moral Hazarddan Implication for Indonesia’s Forest, dalam Asian Development Forum-3, Bangkok.

BIRO. 2001. Indonesia Pulp dan Paper Industry. Jakarta: PT Biro Data Indonesia.

Chang, H. M. 1995. Peracids As A Bleaching Agent: Basics. In: Proc. Emerging Pulping And Bleaching Tech. Workshop. Durham.

Datta, R. 1981. Acidogenic Fermentation of Linocellulose Acid Yield and Connvertion of Componens. Biotechnol. Bioeng 23. 2167–2170.

Deperindag dan APKI. 2001. Industri Pulp dan Kertas 1999-2003: Realisasi 1999-2000 dan Proyeksi 2001-2003. Jakarta: Direktorat Industri Pulp dan Kertas.

Edahwati, L. 2009. Proses deinkin Kertas Koran Bekas Menggunakan Hidrogen peroksida, Jurnal Kimia dan teknologi. ISSN 0216-163X. Hal 322-327.

Fengel, D dan Wegener, G. 1995. Kayu: Kimia, Ultrastruktur, Reaksi - reaksi. Gadjah Mada University Press. Yogyakarta. 77–545.

Fuadi, A.M., dan Sulistyo, P. 2008. Pemutihan Pulp dengan Hidrogen peroksida. Jurnal reaktor, Vol. 12, No. 2. Hlm 123-128.

Fuadi, A.M., dan H. Sulistya. 2008, Pemutihan Pulp dengan Hidrogen Peroksida, Reaktor, 2(12), 123-128.

Hatakeyama, H, Nakano, M.J and Migita, N. 1986. Degradation of Cellulose with Peracetic Acid. Kogua Kgaku Zusshin71 (1), p: 153-156.Hill, R. T., Walsh, P. B., Hollie, J. A. Part I: Peracetic Acid An Effective Alternative For Chlorine Compound Free Delignification of Kraft Pulp. In: Proc. Tappi Pulp Conf., Boston, 1992. P.1219-1230.

Hidayati, S dan Zulferiyenni. 2006. Proses pemutihan dan pengaruhnya menggunakan asam peroksida di dalam media asam asetat terhadap sifat kimia dan derajat putih kertas koran bekas. Jurnal Lamina Media Publikasi ilmiah, Vol. 2, No 2 (78-82).

Jayanudin, 2009, Pemutihan Daun Nanas Menggunakan Hidrogen Peroksida, Jurnal Rekayasa Proses Vol. 3, No 1.

Jääskeläinen, A. S. and , Poppius-Levlin, K. Carbohydrates in peroxyacetic acid bleaching. In: Proc. Interl. Pulp Bleaching Conf., Helsinki. 1998, p.423-428.

[Kemenhut] Kementerian Kehutanan. 2013. Statistik Kehutanan Indonesia 2012. Jakarta (ID): Kementerian Kehutanan.

Lawrence W, McKelvey R.D, Johnson D.C. 1980. The peroxyacetic acid oxidation of a lignin-related β-aryl ether. Svensk Papperstidn 83: 11–18.

Mahagaonkar, M and Paul, B. 1995. Effect of the Deinking on Optical and Physical Properties of Secondary Fibre after Pulping and Flotation. APPITA, 4:6.

Madakadze, I.C., Radiotis, T., . Li, J., Goel, K and. Smith, D.L., (1999), Kraft Pulping Characteristics and Pulping Properties of Warm Season Grasses, Bioresource Technology, 69: 75-78.

Nevell, T.D daan Zeronian, S.H. 1985. Oxidant of cellulose in Cellulose Chemistry and Its applications, Ellis Hardwood Limited Chiccherter-West Sussex, p: 243-265.

Paraskevas, S. 1990. Ink Removal-Various Methods and Their Effectiveness. Recycling Paper:From Fibre to Finished Product, 426-429.

Retnowati, D.S. 2008. Pemutihan enceng gondok menggunakan H2O2 dengan katalisator natrium bikarbonat. Reaktor, Vol. 12, No. 1, Pp. 33-36

Rismijana, J, I.N Indriani dan T Pitariyani. 2003. Penggunaan Enzim Selulase-Hemiselulase pada Proses Deinking Kertas Koran Bekas. Jurnal Matematika dan Sains, Vol. 8, No. 2:67-71.

Sjostrom, E. 1981. Kimia Kayu; Dasar-dasar dan Penggunaan. Edisi ke 2. Gajah Mada University Press. Yogyakarta. 390 Hlm.

Steel, R. G. D and Torrie, J. H. 1990. Prinsip dan Prosedur Statistik, Suatu Pendekatan Biometrik. Gramedia. Jakarta.

Sun R.C, Tomkinson J, Zhu W, Wang SQ . 2000. Delignification of maize stems by peroxymonosulfuric acid, peroxyformic acid, peracetic acid, and hydrogen peroxide. 1. Physicochemical and structural characterization of the solubilized lignins. J Agric Food Chem 48: 1253–1262.

Wildan A, Abdullah, Priyanto A, 2010, Studi Proses Bleaching Serat Kelapa Sebagai Reinforced Fiber, Seminar Rekayasa Kimia dan Proses, ISNN : 1411-4216

Yamani M. 2011. Strategi perlindungan hutan berbasis hukum lokal di enam komunitas adat daerah bengkulu. Jurnal Hukum. 2:175-192.

Yves L, Yumiko U, Michael S, Arif B, Budi S, Oki H. 2010. Eco-floristic sectors and deforestation threats in Sumatra: identifying new conservation area network priorities for ecosystem-based land use planning. Biodiversity & Conservation. 19 (4):1153-1174.

Zuidar, A.S; Hidayati, S dan Pulungan, R.J.A. 2014. Kajian Delignifikasi Pulp Formacell Dari Tandan Kosong Kelapa Sawit Menggunakan Hidrogen Peroksida (H2O2) Dalam Media Asam Asetat. Jurnal Teknologi Industri dan Hasil Pertanian Volume 19 No.2, P. 194-204.