Pemanfaatan kulit buah kakao pada proses alkalisasi biji kakao serta pengaruhnya terhadap mutu kakao bubuk

Neni Cahyati, Eko Heri Purwanto, Selly Harnesa Putri

Abstract

The problem facing the industry of cocoa powder in Indonesia is that cocoa powder on the market has a high fat content, high acidity, a color quality that is not comparable with imported cocoa products, and a variety of flavors and aromas. Alkalization is a method that can handle these problems. Alkalization is a process to improve the quality and appearance of cocoa powder. Alkalization is carried out by adding potassium, magnesium, and others to cocoa. High potassium content can be found in cocoa pod husks. Cocoa pod husks are the main by-product from the cocoa industry, constituting  67 – 76% of the cocoa fruit weight. Cocoa pod husk contains potassium, fiber, and antioxidants that function as biomaterials for food and non-food products. The aims of the study were to determine and evaluate the quality of cocoa powder with the effect of alkalization treatments using cocoa pod husks. The study was carried out at The Indonesian Industrial and Beverage Crops Research Institute, Sukabumi, West Java, from January to June 2022. This study was designed in a factorial completely randomized design. The first factor was the alkaline material, which consisted of two levels (cocoa pod husk and baking soda). The second factor was the concentration, which consisted of 3 levels (1%, 2%, and 3%). The variables observed were the L*, a*, b*, moisture content, ash content, fineness, pH, fat content, protein, antioxidant activity, and organoleptic properties. The results showed that the alkalization process with alkaline material from cocoa pod husk and a concentration of 2% is the best quality characteristic of cocoa powder in accordance with SNI 01-3747-2013.

Keywords

lkalization; Cacao nibs; Cocoa Pod Husk; Physicochemical; Valorization

References

Adeyeye, E. I. 2016. Proximate, Mineral And Antinutrient Compositions Of Natural Cocoa Cake, Cocoa Liquor And Alkalized Cocoa Powders. Journal of Advanced Pharmaceutical Science And Technology, 1(3), 12–28. https://doi.org/10.14302/issn.2328-0182.japst-15-855

Albores, A.M., Aguilar, A.Z.C., Matinez, E.M., Duran, A.V. 2013. Physical and Chemical Degradation of B-aflatoxins during the Roasting and Dutching of Cocoa Liqour. Agricultural Science and Technology, 15, 557–567.

Aprotosoaie, A.C., Luca, S.V., Miron, A. 2016. Flavor Chemistry of Cocoa and Cocoa Products-An Overview. Comprehensive Reviews in Food Science and Food Safety, 15(1), 73–91. https://doi.org/10.1111/1541-4337.12180

Arziyah, D., Mutiar, S. 2021. Effect of alkalization on cocoa paste on the yield of pressed oil. Jurnal Litbang Industri, 11, 97–102.

Aulia, T., Suharyono, U., Yulianto, E. 2018. Analisis Daya Saing Ekspor Biji Dan Produk Olahan Kakao Indonesia (Periode Tahun 2012-2016). Jurnal Administrasi Bisnis (JAB)|Vol, 62(2), 11–20.

Danggi, E., Oge, L. 2013. Pengaruh Penambahan Alkali pada Bungkil Kakao Terhadap Aktivitas Antioksidan dan Penilaian Organoleptik Bubuk Kakao. Teknologi Hasil Pertanian, 2.

David, J., Manurung, G. O. 2014. Perbaikan Mutu Biji Kakao dengan Perlakuan Suhu Pengeringan dan Fermentasi di Kalimantan Barat. Prosiding Seminar Nasional Agroinovasi Spesifik Lokasi Untuk Ketahanan Pangan Pada Era Masyarakat, 1290–1295.

Diansari, A. Z., Suwasono, S., Yuwanti, S. 2015. Karakteristik fisik, kimia, dan mikrobiologis biji kakao kering produksi ptpn xii kebun kalikempit, banyuwangi. Teknologi Hasil Pertanian, 1–7.

Dyer, B. 2003. Alkalized Cocoa Powders. PMCA Production Conference, (57), 128–135.

Garcia, D.V., Esteve, E.P., Baviera, J.M. B. 2020. Changes in cocoa properties induced by the alkalization process: A review. Comprehensive Reviews in Food Science and Food Safety, 19(4), 2200–2221. https://doi.org/10.1111/1541-4337.12581

Hanafi, R.U., Tinaprilla, N. 2017. Daya Saing Komoditas Kakao Indonesia Di Perdagangan Internasional. Forum Agribisnis, 7(1), 1–20. https://doi.org/10.29244/fagb.7.1.1-20

Juliani, M., Mujiharjo, S., Dewi, K.H. 2014. Pengaruh Jenis Alkali dan Lama Perendamana Nibs Terhadap Mutu Bubuk Coklat pada Pembuatan Bubuk Coklat dengan Metode “‘Dutch Process.’” Agroindustri, 4(2), 86–93.

Khaerunnisa, Rejeki, E.S. 2019. Kualitas Kakao Bubuk Dipasaran Kota Makassar. Majalah Teknologi Agro Industri (TEGI), 10(2), 48. https://doi.org/10.46559/tegi.v10i2.4547

Li, Y., Zhu, S., Feng, Y., Xu, F., Ma, J., Zhong, F. 2014. Influence of Alkalization Treatment on the Color Quality and the Total Phenolic and Anthocyanin Contents in Cocoa Powder. Food Science and Biotechnology, 23(1)(February), 59–63. https://doi.org/10.1007/s10068-014-0008-5

Lutfinandha, M. A., Drasiawati, N. S. 2020. Pengaruh Waktu Perendaman Serat Pada Larutan Natrium Bikarbonat (NaHCO3) Terhadap Kekuatan Tarik Dan Struktur Mikro Komposit Serat Kulit Batang Kersen - Poliester. Jurnal Teknik Mesin, 8(2), 9–18.

Miller, K.B., Hurst, W.J., Payne, M.J., Stuart, D.A., Apgar, J., Sweigart, D.S., Ou, B. 2008. Impact of alkalization on the antioxidant and flavanol content of commercial cocoa powders. Journal of Agricultural and Food Chemistry, 56(18), 8527–8533. https://doi.org/10.1021/jf801670p

Misnawi, S., Jinap, S., Teguh, W., Novrita, P. 2006. Pengaruh Konsentrasi Alkali dan Suhu Koncing Terhadap Cita Rasa, Kekerasan dan Warna Permen Cokelat. Pelita Perkebunan, 22(2), 119–135.

Osundahunsi, O.F., Bolade, M.K., Akinbinu, A.A. 2007. Effect of cocoa shell ash as an alkalizing agent on cocoa products. Journal of Applied Sciences, 7(12), 1674–1678. https://doi.org/10.3923/jas.2007.1674.1678

Purnamawati, H., Utami, B. 2014. Pemanfaatan Limbah Kulit Buah Kakao (Theobroma cocoa L) Sebagai Adsorben Zat Warna Rhodamin B. Prosiding Seminar Nasional Fisika Dan Pendidikan Fisika (SNFPF), 5(1), 12.

Purwanto, E. H., Iflah, T., Aunillah, A. 2020. Pengaruh Alkalisasi Nib Kakao terhadap Kandungan Kimia dan Warna Bubuk Kakao. Seminar Nasional Lahan Suboptimal, (1), 253–260.

Rodriguez, P., Elevina, P., Guzman, R. 2009. Effect of the types and concentrations of alkali on the color of cocoa liquor. Society of Chemical Industry, 89(January), 1186–1194. https://doi.org/10.1002/jsfa.3573

Siagian, I.V.J. 2016. Outlook Kakao. In L. Nuryati & A. Yasin (Eds.), Komoditas Pertanian Subsektor Perkebunan. Pusat Data dan Sistem Informasi Pertanian.

Sioriki, E., Alhakim, F., Triharyogi, H., Tuenter, E., Cazin, C.S.J., Nolan, S.P., Dewettinck, K. 2021. Impact of alkalization conditions on the phytochemical content of cocoa powder and the aroma of cocoa drinks. Food Science & Technology, 145(February), 111181. https://doi.org/10.1016/j.lwt.2021.111181

Siswati. 2020. Analisa Kadar Air dan Kadar Abu pada Simplisia Temu Giring (Curcumae heyneana) dan Simplisia Kunyit (Curcumae domestica) di Balai Riset dan Standarisasi Industri Medan. Tugas Akhir Program Studi D3 Analis Farmasi Dan Makanan, 1–35.

Stanley, T. H., Smithson, A. T., Neilson, A.P., Anantheswaran, R.C., Lambert, J.D. 2015). Analysis of Cocoa Proanthocyanidins Using Reversed Phase High- Performance Liquid Chromatography and Electrochemical Detection: Application to Studies on the Effect of Alkaline Processing. Agriculture and Food Chemistry. https://doi.org/10.1021/acs.jafc.5b02661

Sukeksi, L., Hidayati, R.D., Paduana, A.B. 2017. Leaching Kalium Dari Abu Kulit Coklat (Theobroma Cacao L.) Menggunakan Pelarut Air. Teknik Kimia USU, 6(2), 30–34.

Sunarto, W., Mantini, S. 2010. Penetralan dan Adsorbsi Minyak Goreng Bekas Menjadi Minyak Goreng Layak Konsumsi. Kimia, 8(1), 46–56.

Widayat, H.P. 2013. Perbaikan Mutu Bubuk Kakao Melalui Proses Ekstraksi Lemak dan Alkalisasi. Jurnal Teknologi & Industri Pertanian Indonesia, 5(2), 12–16. https://doi.org/10.17969/jtipi.v5i2.1003

Williams, W.B., Cuvelier, M.E., Berset, C. 1995. Use of a Free Radical Method to Evaluate Antioxidant Activity. Laboratoire de Chimie Des Substances Naturelles, 30(1), 25–30.

Yahaya, L.E., Ajao, A.A., Jayeola, C.O., Igbinadolor, R.O., Mokwunye, F.C. 2012. Soap Production from Agricultural Residues - a Comparative Study. American Journal of Chemistry, 2(1), 7–10. https://doi.org/10.5923/j.chemistry.20120201.02

DOI

https://doi.org/10.21107/agrointek.v18i4.15746

Metrics

Refbacks





Copyright (c) 2024 Neni Cahyati, Eko Heri Purwanto, Selly Harnesa Putri

Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 International License.