Adsorpsi Logam Kadmium dalam Limbah Cair Buatan Menggunakan Biosorben Kulit Pisang Mas (Musa acuminate colla)

Djamilah Arifiyana, Ratih Kusuma Wardani

Abstract

Mas banana (Musa acuminata Colla) peel is a type of household waste as well as agricultural waste whose utilization still needs to be improved. In addition, among various types of heavy metals that are dangerous as contaminants in the environment, cadmium metal is a metal that is very dangerous to health even in very small amounts. Therefore, this study aims to not only utilize the waste of Mas banana peel (Musa acuminata Colla) as a biosorbent, but also to determine the optimum conditions needed to reduce cadmium metal which involves several test parameters, namely stirring time, pH and mass of biosorbent. Variations of stirring time used include 10, 20, 30, 35, and 45 minutes; variations in pH used include 1, 2, 3, 4, and 5, while variations in the mass of biosorbent used include 0.5; 1; 1.5; 2 and 2.5 grams. The results showed that the optimum conditions were obtained at a mixing time of 35 minutes, pH 5, and a mass of 2 grams of biosorbent with a reduction percentage value of 78.45%. This percentage indicates that Mas banana peel can be used as a natural adsorbent for cadmium metal. In addition, the results of the FT-IR analysis of the Mas banana peel biosorbent showed that Mas banana peel has a functional group that plays a role in the heavy metal adsorption process.

Keywords

biosorption, Cadmium, Mas Banana peels

References

Abdi, C., Khair, R. M., & Saputra, D. M. W. (2015). Pemanfaatan Limbah Kulit Pisang Kepok (Musa acuminate L.) sebagai Karbon Aktif untuk Pengolahan Air Sumur Kota Banjarbaru: Fe dan Mn. Jukung Jurnal Teknik Lingkungan, 1(1), 8–15.

Al-Homaidan, A. A., Alabdullatif, J. A., Al-Hazzani, A. A., Al-Ghanayem, A. A., & Alabbad, A. F. (2015). Adsorptive removal of cadmium ions by Spirulina platensis dry biomass. Saudi Journal of Biological Sciences, 22(6), 795–800. https://doi.org/10.1016/j.sjbs.2015.06.010

Alifaturrahma, P., & Hendriyanto, O. (2018). Pemanfaatan Kulit Pisang Kepok sebagai Adsorben untuk Menyisihkan Logam Cu. Jurnal Ilmiah Teknik Lingkungan, 8(2), 105–111.

Anwar, J., Shafique, U., Waheed-uz-Zaman, Salman, M., Dar, A., & Anwar, S. (2010). Removal of Pb(II) and Cd(II) from water by adsorption on peels of banana. Bioresource Technology, 101(6), 1752–1755. https://doi.org/10.1016/j.biortech.2009.10.021

Arifiyana, D., & Devianti, V. A. (2020). Biosorpsi Logam Besi (Fe) dalam Media Limbah Cair Artifisial Menggunakan Adsorben Kulit Pisang Kepok (Musa acuminate). Jurnal Kimia Riset, 5(1), 1–8. https://doi.org/10.20473/jkr.v5i1.20245

Arifiyana, D., & Devianti, V. A. (2021). Biosorption of Fe (II) Ions from Aqueous Solution Using Kepok Banana Peel (Musa Acuminate). Jurnal Kimia Dan Pendidikan Kimia (JKPK), 6(2), 206–215. https://doi.org/10.1063/5.0043112

Arninda, A., Sjahrul, M., & Zakir, M. (2014). Adsorpsi Ion Logam Pb(II) dengan Menggunakan Kulit Pisang Kepok (Musa paradisiaca Linn). Indonesia Chimica Acta, 7(2), 21–26.

Baloga, H., Walanda, D. K., & Hamzah, B. (2019). Pembuatan Arang dari Kulit Nangka (Artocarpus heterophyllus) Sebagai Adsorben Terhadap Kadmium dan Nikel Terlarut. Jurnal Akademika Kimia, 8(February), 28–33. https://doi.org/10.22487/j24775185.2019.v8.i1.2349

Darge, A., & Mane, S. J. (2013). Treatment of Industrial Wastewater by using Banana Peels and Fish Scales. International Journal of Science and Research (IJSR) ISSN (Online Index Copernicus Value Impact Factor, 14(7), 2319–7064. Retrieved from www.ijsr.net

Darmayanti, D., Rahman, N., & Supriadi, S. (2012). Adsorpsi Timbal (Pb) dan Zink (Zn) dari Larutannya Menggunakan Arang Hayati (Biocharcoal) Kulit Pisang Kepok Berdasarkan Variasi pH. Jurnal Akademika Kimia, 1(4), 159–165.

Deshmukh, P. D., Khadse, G. K., Shinde, V. M., & Labhasetwar, P. (2017). Cadmium Removal from Aqueous Solutions Using Dried Banana Peels as An Adsorbent: Kinetics and Equilibrium Modeling. Journal of Bioremediation & Biodegradation, 08(03), 1–7. https://doi.org/10.4172/2155-6199.1000395

Fauici, M. (2017). Adsorpsi Ion Pb (II) dan Cr (VI) Menggunakan Arang Kulit Pisang Kepok (Musa paradisiaca Linn) pada Limbah Cair Industri (Studi Kasus PT. SERMANI STEEL). Universitas Hasanudin.

Giannakoudakis, D. A., Hosseini-Bandegharaei, A., Tsafrakidou, P., Triantafyllidis, K. S., Kornaros, M., & Anastopoulos, I. (2018). Aloe vera waste biomass-based adsorbents for the removal of aquatic pollutants: A review. Journal of Environmental Management, 227(August), 354–364. https://doi.org/10.1016/j.jenvman.2018.08.064

Gong, R., Ding, Y., Liu, H., Chen, Q., & Liu, Z. (2005). Lead biosorption and desorption by intact and pretreated spirulina maxima biomass. Chemosphere, 58(1), 125–130. https://doi.org/10.1016/j.chemosphere.2004.08.055

Hossain, A., Ngo, H., Guo, W., & Nguyen, V. (2012). Biosorption of Cu(II) From Water by Banana Peel Based Biosorbent: Experiments and Models of Adsorption and Desorption. 2(1), 87–104.

Jasem, N. A. (2015). Removal of Copper(II) and Cadmium(II) ions from Aqueous Solutions Using Banana Peels and Bentonite Clay as Adsorbents. Journal of Engineering and Development, 19(4), 49–68.

Jena, S., & Sahoo, R. K. (2017). Removal of Pb (II) from Aqueous Solution Using Fruits Peel as a Low Cost Adsorbent. International Journal of Science, Engineering and Technology, 5(1), 5–13.

Kosasih, A. N., Febrianto, J., Sunarso, J., Ju, Y. H., Indraswati, N., & Ismadji, S. (2010). Sequestering of Cu(II) from aqueous solution using cassava peel (Manihot esculenta). Journal of Hazardous Materials, 180, 366–374. https://doi.org/10.1016/j.jhazmat.2010.04.040

Kumari, P. (2017). a Low Cost Material , Banana Peel for the Removal of Lead (II) From Aqueous Solutions. International Research Journal of Engineering and Technology(IRJET), 4(6), 1404–1406. Retrieved from https://irjet.net/archives/V4/i6/IRJET-V4I6257.pdf

Kwikima, M. M., Mateso, S., & Chebude, Y. (2021). Potentials of agricultural wastes as the ultimate alternative adsorbent for cadmium removal from wastewater. A review. Scientific African, 13, e00934. https://doi.org/10.1016/j.sciaf.2021.e00934

Mohd Salim, R., Khan Chowdhury, A. J., Rayathulhan, R., Yunus, K., & Sarkar, M. Z. I. (2016). Biosorption of Pb and Cu from aqueous solution using banana peel powder. Desalination and Water Treatment, 57(1), 303–314. https://doi.org/10.1080/19443994.2015.1091613

Pandharipande, S., & Deshpande, R. (2013). Synthesis & Effectiveness Study Of Banana Peel Adsorbent & Artificial Neural Network Modeling In Removal Of Cu ( II ) Ions From Aqueous Solution. 3(6), 730–734.

Purnama, P. E., Dewi, I. G. A. K. S. P., & Ratnayani, K. (2015). Kapasitas Adsorpsi Beberapa Jenis Kulit Pisang Teraktivasi Naoh Sebagai Adsorben Logam Timbal (Pb). Jurnal Kimia, 9(2), 196–202.

Sirilert, M., & Maikrang, K. (2018). Adsorption Isotherm of Some Heavy Metals in Water on Unripe and Ripe Peel of Banana. Naresuan University Journal : Science and Technology, 26(1), 128–141. Retrieved from www.journal.nu.ac.th/NUJST/article/view/1741/1239 -

Siringo-Ringo, E. P. (2019). Pengaruh Waktu Kontak, pH dan Dosis Adsorben Dalam Penurunan Kadar Pb Dan Cd Menggunakan Adsorben Dari Kulit Pisang. Universitas Sumatra Utara.

Sutapa, I. W., Siahay, V. P. D., & Tanasale, M. F. J. D. P. (2014). Adsorpsi Ion Logam Cu2+ Pada Pektin Dari Kulit Pisang Tongka Langit (Musa Speices van Balbisiana). Ind.J.Chem.Res, 1(January), 72–77.

Taralgatti, P. D. (2016). Removal of copper from Waste water by using potato and banana peels as bio-adsorbent. International Journal of Science, Engineering and Technology Research (IJSETR), 5(10), 2278–7798. Retrieved from http://ijsetr.org/wp-content/uploads/2016/10/IJSETR-VOL-5-ISSUE-10-3038-3040.pdf

Wardani, G. A., & Wulandari, W. T. (2018). Pemanfaatan Limbah Kulit Pisang Kepok (Musa acuminate) sebagai Biosorben Ion Timbal(II). Jurnal Kimia VALENSI, 4(2), 143–148. https://doi.org/10.15408/jkv.v4i2.6918

Waseem, S., Din, M. I., Nasir, S., & Rasool, A. (2014). Evaluation of Acacia nilotica as a non conventional low cost biosorbent for the elimination of Pb(II) and Cd(II) ions from aqueous solutions. Arabian Journal of Chemistry, 7(6), 1091–1098. https://doi.org/10.1016/j.arabjc.2012.03.020

DOI

https://doi.org/10.21107/rekayasa.v14i3.12391

Metrics

Refbacks

  • There are currently no refbacks.


Copyright (c) 2021 Djamilah Arifiyana, Ratih Kusuma Wardani

Creative Commons License
This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.